On the influence of clustering processes in the liquid structure on Raman scattering

A mathematical relation has been obtained that makes it possible to calculate the polarizability of a polyatomic molecule in structure cluster. It is shown scattered frequencies Raman effect are proportional square root number particles most probable (or average) cluster liquid structure. The appearance far part spectrum region caused by processes intermolecular interactions clusters and disintegration or formation systems disordered condensed media. According proposed model experimental data frequency range 20–1300 cm -1 , carried out comparison values calculated their mutual position, which adequacy model. methods statistics statistical thermodynamics make expand capabilities classical theory scattering liquids predict position spectral bands spectra long-wavelength spectrum. revealed breakdown associated with correlations stable (in terms particles) medium Fibonacci numbers.